Locks are used for mutual exclusion. When you want to ensure that a piece of code is atomic, put a lock around it. You could theoretically use a binary semaphore to do this, but that's a special case.
Semaphores and condition variables build on top of the mutual exclusion provide by locks and are used for providing synchronized access to shared resources. They can be used for similar purposes.
A condition variable is generally used to avoid busy waiting (looping repeatedly while checking a condition) while waiting for a resource to become available. For instance, if you have a thread (or multiple threads) that can't continue onward until a queue is empty, the busy waiting approach would be to just doing something like:
//pseudocode
while(!queue.empty())
{
sleep(1);
}
The problem with this is that you're wasting processor time by having this thread repeatedly check the condition. Why not instead have a synchronization variable that can be signaled to tell the thread that the resource is available?
//pseudocode
syncVar.lock.acquire();
while(!queue.empty())
{
syncVar.wait();
}
//do stuff with queue
syncVar.lock.release();
Presumably, you'll have a thread somewhere else that is pulling things out of the queue. When the queue is empty, it can call syncVar.signal() to wake up a random thread that is sitting asleep on syncVar.wait() (or there's usually also a signalAll() or broadcast() method to wake up all the threads that are waiting).
I generally use synchronization variables like this when I have one or more threads waiting on a single particular condition (e.g. for the queue to be empty).
Semaphores can be used similarly, but I think they're better used when you have a shared resource that can be available and unavailable based on some integer number of available things. Semaphores are good for producer/consumer situations where producers are allocating resources and consumers are consuming them.
Think about if you had a soda vending machine. There's only one soda machine and it's a shared resource. You have one thread that's a vendor (producer) who is responsible for keeping the machine stocked and N threads that are buyers (consumers) who want to get sodas out of the machine. The number of sodas in the machine is the integer value that will drive our semaphore.
Every buyer (consumer) thread that comes to the soda machine calls the semaphore down() method to take a soda. This will grab a soda from the machine and decrement the count of available sodas by 1. If there are sodas available, the code will just keep running past the down() statement without a problem. If no sodas are available, the thread will sleep here waiting to be notified of when soda is made available again (when there are more sodas in the machine).
The vendor (producer) thread would essentially be waiting for the soda machine to be empty. The vendor gets notified when the last soda is taken from the machine (and one or more consumers are potentially waiting to get sodas out). The vendor would restock the soda machine with the semaphore up() method, the available number of sodas would be incremented each time and thereby the waiting consumer threads would get notified that more soda is available.
The wait() and signal() methods of a synchronization variable tend to be hidden within the down() and up() operations of the semaphore.
Certainly there's overlap between the two choices. There are many scenarios where a semaphore or a condition variable (or set of condition variables) could both serve your purposes. Both semaphores and condition variables are associated with a lock object that they use to maintain mutual exclusion, but then they provide extra functionality on top of the lock for synchronizing thread execution. It's mostly up to you to figure out which one makes the most sense for your situation.
That's not necessarily the most technical description, but that's how it makes sense in my head.